Welcome to HPSynC
A Gateway for High-Pressure Scientists to Beamlines of the APS

Pressure-Induced New Topological Weyl Semimetal Phase in TaAs
TaAs
We report a new pressure-induced phase in TaAs with different Weyl fermions than the ambient structure with the aid of theoretical calculations, experimental transport and synchrotron structure investigations up to 53 GPa. We show that TaAs transforms from an ambient I41md PHASE (t-TaAs) to a high-pressure hexagonal P-6m2 (h-TaAs) phase at 14 GPa, along with changes of the electronic state from containing 24 Weyl nodes distributed at two energy levels to possessing 12 Weyl nodes at an isoenergy level, which substantially reduces the interference between the surface and bulk states.
More...

Enhanced Structural Stability and Photo Responsiveness of CH3NH3SnI3 Perovskite via Pressure-Induced Amorphization and Recrystallization
CH3NH3Snl3
An organic-inorganic halide CH3NH3Snl3 perovskite with significantly improved structural stability is obtained via pressure-induced amorphization and recrystallization. In situ high-pressure resistance measurements reveal an increased electrical conductivity by 300% in the pressure-treated perovskite. Photocurrent measurements also reveal a substatial enhancement in visible-light reponsiveness. The mechanism underlying the enhanced properties is shown to be associated with the pressure-induced strucural modification.
More...

Giant Pressure-Driven Lattice Collapse Coupled with Intermetallic Bonding and Spin-State Transition in Manganese Chalcogenides
Giant Pressure-Driven Lattice Collapse
Materials with an abrupt volume collapse of more than20% during a pressure-induced phase transition are rarely reported. In such an intriguing phenomenon, the lattice may be coupled with dramatic changes of orbital and/or the spin-state of transition metal. A combined in situ crystallography and electron spin-state study to probe the mechanism of the pressure-driven lattice collapse in MnS and MnSe is presented.
More...

Synthesis of Sodium Polyhydrides at High Pressures
Synthesis of sodium polyhydrides at high pressure
The only known compound of sodium and hydrogen is archetypal ionic NaH. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry have had only limited success in spite of several theoretical predictions. Here we report the first observation of the formation of polyhydrides of Na (NaH3 and NaH7) above 40GPa and 2,000 K.
More...

See more...